Safety data sheet

 SECTION 1. Identification of the substance/mixture and of the company/undertaking.	

 1.1. Product identifier.	
 Code:	CSL3805-35601786	
 Product name.	PROFESSIONAL DEGREASER - CERAMIC HOBS 	

 1.2. Relevant identified uses of the substance or mixture and uses advised against.	
 Intended use.	Detergent	

 1.3. Details of the supplier of the safety data sheet.	
 Name.	DIANOS SRL 	
 Full address.	VIA S. PELLICO 19 	
 District and Country.	20093  COLOGNO MONZESE (MI) 	
 	ITALIA 	
 	Tel. +39022542933 	
 	Fax. +390227300792 	
 e-mail address of the competent person.		
 responsible for the Safety Data Sheet.	massimo.zibra@dianos.net 	

 1.4. Emergency telephone number.	
 For urgent inquiries refer to.	+39022542933 Mon-Fri 9.00-18.00	

 SECTION 2. Hazards identification.	

 2.1. Classification of the substance or mixture.	

The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP).
However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data sheet with appropriate information, compliant to EC Regulation 1907/2006 and subsequent amendments.
Hazard classification and indication:

 2.2. Label elements.	

Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements.

 Hazard pictograms:	--	

 Signal words:	--	

Hazard statements:

Precautionary statements:
 	--	
 P101	If medical advice is needed, have product container or label at hand.	
 P102	Keep out of reach of children.	
 P103	Read label before use.	

Ingredients according to Regulation (EC) No. 648/2004

 Less than 5%	anionic surfactants 	

perfumes, 

 2.3. Other hazards.	

On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%.

 SECTION 3. Composition/information on ingredients.	

 3.1. Substances.	

Information not relevant.

 3.2. Mixtures.	

Contains:

The full wording of hazard (H) phrases is given in section 16 of the sheet.
 Identification.		Classification 1272/2008 (CLP).		
 INERT				
 CAS.   -	50 ≤ x <  100			
 EC.   -				
 INDEX.   -				
 2-(2-BUTOXYETHOXY)ETHANOL				
 CAS.   112-34-5	5 ≤ x <  10	Eye Irrit. 2 H319		
 EC.   203-961-6				
 INDEX.   603-096-00-8				
 BENZYL ALCOHOL				
 CAS.   100-51-6	1 ≤ x <  5	Acute Tox. 4 H302, Acute Tox. 4 H332		
 EC.   202-859-9				
 INDEX.   603-057-00-5				

 SECTION 4. First aid measures.	

 4.1. Description of first aid measures.	

EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 30-60 minutes, opening the eyelids fully. Get medical advice/attention.
SKIN: Remove contaminated clothing. Rinse skin with a shower immediately. Get medical advice/attention.
INGESTION: Have the subject drink as much water as possible. Get medical advice/attention. Do not induce vomiting unless explicitly authorised by a doctor.
INHALATION: Get medical advice/attention immediately. Remove victim to fresh air, away from the accident scene. If the subject stops breathing, administer artificial respiration. Take suitable precautions for rescue workers.

 4.2. Most important symptoms and effects, both acute and delayed.	

Specific information on symptoms and effects caused by the product are unknown.
For symptoms and effects caused by the contained substances, see chap. 11.

 4.3. Indication of any immediate medical attention and special treatment needed.	

Information not available.

 SECTION 5. Firefighting measures.	

 5.1. Extinguishing media.	

SUITABLE EXTINGUISHING EQUIPMENT
Choose the most appropriate extinguishing equipment for the specific case.
UNSUITABLE EXTINGUISHING EQUIPMENT
None in particular.

 5.2. Special hazards arising from the substance or mixture.	

HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE
The product is neither flammable nor combustible.

 5.3. Advice for firefighters.	

SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS
Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137).

 SECTION 6. Accidental release measures.	

 6.1. Personal precautions, protective equipment and emergency procedures.	

Block the leakage if there is no hazard.
Wear suitable protective equipment (including personal protective equipment referred to under Section 8 of the safety data sheet) to prevent any contamination of skin, eyes and personal clothing. These indications apply for both processing staff and those involved in emergency procedures.

 6.2. Environmental precautions.	

The product must not penetrate into the sewer system or come into contact with surface water or ground water.

 6.3. Methods and material for containment and cleaning up.	

Collect the leaked product into a suitable container. If the product is flammable, use explosion-proof equipment. Evaluate the compatibility of the container to be used, by checking section 10. Absorb the remainder with inert absorbent material.
Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13.

 6.4. Reference to other sections.	

Any information on personal protection and disposal is given in sections 8 and 13.

 SECTION 7. Handling and storage.	

 7.1. Precautions for safe handling.	

Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the environment. Do not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering places in which people eat.

 7.2. Conditions for safe storage, including any incompatibilities.	

Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Keep containers away from any incompatible materials, see section 10 for details.

 7.3. Specific end use(s).	

Information not available.

 SECTION 8. Exposure controls/personal protection.	

 8.1. Control parameters.	

Regulatory References:

 DEU	Deutschland	MAK-und BAT-Werte-Liste 2012	
 ITA	Italia	Decreto Legislativo 9 Aprile 2008, n.81	
 EU	OEL EU	Directive 2009/161/EU; Directive 2006/15/EC; Directive 2004/37/EC; Directive 2000/39/EC.	
 	TLV-ACGIH	ACGIH 2016	

 2-(2-BUTOXYETHOXY)ETHANOL	
 Threshold Limit Value.	
 Type	Country	TWA/8h		STEL/15min				
 		mg/m3	ppm	mg/m3	ppm			
 AGW	DEU	  67	  10	100,5	  15			
 MAK	DEU	  67	  10	100,5	  15			
 VLEP	ITA	67,5	  10	101,2	  15			
 OEL	EU	67,5	  10	101,2	  15			
 TLV-ACGIH		  66	  10					

Legend:

(C) = CEILING   ;   INHAL = Inhalable Fraction   ;   RESP = Respirable Fraction   ;   THORA = Thoracic Fraction.

 8.2. Exposure controls.	

As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is well aired through effective local aspiration. Personal protective equipment must be CE marked, showing that it complies with applicable standards.

HAND PROTECTION
Protect hands with category III work gloves (see standard EN 374).
The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability.
The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on the duration and type of use.

SKIN PROTECTION
Wear category I professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body with soap and water after removing protective clothing.

EYE PROTECTION
Wear airtight protective goggles (see standard EN 166).

RESPIRATORY PROTECTION
If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type A filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required.
Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the threshold values considered. The protection provided by masks is in any case limited.
If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529.

ENVIRONMENTAL EXPOSURE CONTROLS.

The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure compliance with environmental standards.

 SECTION 9. Physical and chemical properties.	

 9.1. Information on basic physical and chemical properties.	

 Appearance	liquid	
 Colour	light blue	
 Odour	perfumed	
 Odour threshold.	Not available.	
 pH.	10,5+/-0,5	
 Melting point / freezing point.	Not available.	
 Initial boiling point.	100 °C.	
 Boiling range.	Not available.	
 Flash point.		
 Evaporation Rate	Not available.	
 Flammability of solids and gases	Not available.	
 Lower inflammability limit.	46 °C.	
 Upper inflammability limit.	Not available.	
 Lower explosive limit.	Not available.	
 Upper explosive limit.	Not available.	
 Vapour pressure.	Not available.	
 Vapour density	Not available.	
 Relative density.	Not available.	
 Solubility	insoluble	
 Partition coefficient: n-octanol/water	Not available.	
 Auto-ignition temperature.	Not available.	
 Decomposition temperature.	Not available.	
 Viscosity	Not available.	
 Explosive properties	Not available.	
 Oxidising properties	Not available.	

 9.2. Other information.	

 Total solids (250°C / 482°F)	90,96 %	
 VOC (Directive 2010/75/EC) :	0	
 VOC (volatile carbon) :	0	

 SECTION 10. Stability and reactivity.	

 10.1. Reactivity.	

There are no particular risks of reaction with other substances in normal conditions of use.

BENZYL ALCOHOL
Decomposes at temperatures above 870°C/1598°F.Possibility of explosion.

 10.2. Chemical stability.	

The product is stable in normal conditions of use and storage.

 10.3. Possibility of hazardous reactions.	

No hazardous reactions are foreseeable in normal conditions of use and storage.

2-(2-BUTOXYETHOXY)ETHANOL
May react with: oxidising substances.May form peroxides with: oxygen.Develops hydrogen on contact with: aluminium.May form explosive mixtures with: air.

BENZYL ALCOHOL
May react dangerously with: hydrobromic acid,iron,oxidising agents,sulphuric acid.Risk of explosion on contact with: phosphorus trichloride.

 10.4. Conditions to avoid.	

None in particular. However the usual precautions used for chemical products should be respected.

2-(2-BUTOXYETHOXY)ETHANOL
Avoid exposure to: air.

BENZYL ALCOHOL
Avoid exposure to: air,sources of heat,naked flames.

 10.5. Incompatible materials.	

2-(2-BUTOXYETHOXY)ETHANOL
Incompatible with: oxidising substances,strong acids,alkaline metals.

BENZYL ALCOHOL
Incompatible with: sulphuric acid,oxidising substances,aluminium.

 10.6. Hazardous decomposition products.	

2-(2-BUTOXYETHOXY)ETHANOL
May develop: hydrogen.

 SECTION 11. Toxicological information.	

In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it contains, using the criteria specified in the applicable regulation for classification.
It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the toxicological effects of exposure to the product.

 11.1. Information on toxicological effects.	

2-(2-BUTOXYETHOXY)ETHANOLCan be absorbed by inhalation, ingestion and skin contact; it is irritant to the skin and especially to the eyes; spleen damage may occur. Inhalation is unlikely to occur at room temperature due to the low vapour tension of the substance.

ACUTE TOXICITY.

LC50 (Inhalation - vapours) of the mixture:> 20 mg/l
LC50 (Inhalation - mists / powders) of the mixture:Not classified (no significant component).
LD50 (Oral) of the mixture:>2000 mg/kg
LD50 (Dermal) of the mixture:Not classified (no significant component).

2-(2-BUTOXYETHOXY)ETHANOL
LD50 (Oral).3384 mg/kg Rat
LD50 (Dermal).2700 mg/kg Rabbit

BENZYL ALCOHOL
LD50 (Oral).1230 mg/kg Rat
LD50 (Dermal).2000 mg/kg Rabbit
LC50 (Inhalation).> 4,1 mg/l/4h Rat

SKIN CORROSION / IRRITATION.
Does not meet the classification criteria for this hazard class.
SERIOUS EYE DAMAGE / IRRITATION.
Does not meet the classification criteria for this hazard class.
RESPIRATORY OR SKIN SENSITISATION.
Does not meet the classification criteria for this hazard class.
GERM CELL MUTAGENICITY.
Does not meet the classification criteria for this hazard class.
CARCINOGENICITY.
Does not meet the classification criteria for this hazard class.
REPRODUCTIVE TOXICITY.
Does not meet the classification criteria for this hazard class.
STOT - SINGLE EXPOSURE.
Does not meet the classification criteria for this hazard class.
STOT - REPEATED EXPOSURE.
Does not meet the classification criteria for this hazard class.
ASPIRATION HAZARD.
Does not meet the classification criteria for this hazard class.
 SECTION 12. Ecological information.	

Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways or contaminate soil or vegetation.

 12.1. Toxicity.	
Information not available.

 12.2. Persistence and degradability.	

 2-(2-BUTOXYETHOXY)ETHANOL			
 Solubility in water.		1000 - 10000 mg/l	
Rapidly biodegradable.

 BENZYL ALCOHOL			
Rapidly biodegradable.

 12.3. Bioaccumulative potential.	

 2-(2-BUTOXYETHOXY)ETHANOL			
 Partition coefficient: n-octanol/water.		1 	

 BENZYL ALCOHOL			
 Partition coefficient: n-octanol/water.		1,1 	

 12.4. Mobility in soil.	

Information not available.

 12.5. Results of PBT and vPvB assessment.	

On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%.

 12.6. Other adverse effects.	

Information not available.

 SECTION 13. Disposal considerations.	

 13.1. Waste treatment methods.	

Reuse, when possible. Neat product residues should be considered special non-hazardous waste.
Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations.
CONTAMINATED PACKAGING 
Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.

 SECTION 14. Transport information.	

The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail (RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations.

14.1. UN number.

Not applicable.

14.2. UN proper shipping name.

Not applicable.

14.3. Transport hazard class(es).

Not applicable.

14.4. Packing group.

Not applicable.

14.5. Environmental hazards.

Not applicable.

14.6. Special precautions for user.

Not applicable.

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code.

Information not relevant.

 SECTION 15. Regulatory information.	

Biodegradabilità tensioattivi presenti in formula conforme al regolamento CE 648/2004
DM 7/09/2002 Recepimento della direttiva2001/58/CE riguardante le modalità di informazione su sostanze e preparati pericolosi immessi in commercio
Direttiva 2001/58/CE
Dlgs 14 marzo 2003 N°65- attuazione delle direttive 1999/45/CE e 2001/60/CE concernente classificazione, imballaggio ed etchettatura delle sostanze pericolose.

 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture.	

Seveso Category - Directive 2012/18/EC: 

Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006.

Contained substance.

 Point.	55	2-(2-BUTOXYETHOXY)ETHANOL	

Substances in Candidate List (Art. 59 REACH).

On the basis of available data, the product does not contain any SVHC in percentage greater than 0,1%.

Substances subject to authorisarion (Annex XIV REACH).

None.

Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012:

None.

Substances subject to the Rotterdam Convention:

None.

Substances subject to the Stockholm Convention:

None.

Healthcare controls.

Information not available.

Regulation (EC) No. 648/2004.

Ingredients according to Regulation (EC) No. 648/2004.

 15.2. Chemical safety assessment.	

No chemical safety assessment has been processed for the mixture and the substances it contains.

 SECTION 16. Other information.	

Text of hazard (H) indications mentioned in section 2-3 of the sheet:

 Acute Tox. 4	Acute toxicity, category 4		
 Eye Irrit. 2	Eye irritation, category 2		
 H302	Harmful if swallowed.		
 H332	Harmful if inhaled.		
 H319	Causes serious eye irritation.		
 EUH210	Safety data sheet available on request.		

LEGEND:
- ADR: European Agreement concerning the carriage of Dangerous goods by Road
- CAS NUMBER: Chemical Abstract Service Number 
- CE50: Effective concentration (required to induce a 50% effect)
- CE NUMBER: Identifier in ESIS (European archive of existing substances)
- CLP: EC Regulation 1272/2008
- DNEL: Derived No Effect Level
- EmS: Emergency Schedule
- GHS: Globally Harmonized System of classification and labeling of chemicals
- IATA DGR: International Air Transport Association Dangerous Goods Regulation
- IC50: Immobilization Concentration 50% 
- IMDG: International Maritime Code for dangerous goods
- IMO: International Maritime Organization
- INDEX NUMBER: Identifier in Annex VI of CLP
- LC50: Lethal Concentration 50%
- LD50: Lethal dose 50%
- OEL: Occupational Exposure Level
- PBT: Persistent bioaccumulative and toxic as REACH Regulation 
- PEC: Predicted environmental Concentration
- PEL: Predicted exposure level
- PNEC: Predicted no effect concentration
- REACH: EC Regulation 1907/2006 
- RID: Regulation concerning the international transport of dangerous goods by train
- TLV: Threshold Limit Value
- TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure.
- TWA STEL: Short-term exposure limit
- TWA: Time-weighted average exposure limit
- VOC: Volatile organic Compounds
- vPvB: Very Persistent and very Bioaccumulative as for REACH Regulation
- WGK: Water hazard classes (German).

GENERAL BIBLIOGRAPHY
1. Regulation (EU) 1907/2006 (REACH) of the European Parliament
2. Regulation (EC) 1272/2008 (CLP) of the European Parliament
3. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament
4. Regulation (EU) 2015/830 of the European Parliament
5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament
6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament
7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament
8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament
9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament
10. Regulation (EU) 2015/1221 (VII Atp. CLP) of the European Parliament
- The Merck Index. - 10th Edition
- Handling Chemical Safety
- INRS - Fiche Toxicologique (toxicological sheet)
- Patty - Industrial Hygiene and Toxicology
- N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition
- ECHA website
Note for users:
The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the suitability and thoroughness of provided information according to each specific use of the product.
This document must not be regarded as a guarantee on any specific product property.
The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health and safety laws and regulations. The producer is relieved from any liability arising from improper uses.
Provide appointed staff with adequate training on how to use chemical products.